# Materials of construction

Author: Katie Johnson [2015]

Stewards: Jian Gong and Fengqi You

# Material Properties

There are several properties of a material that can affect its suitability for the design. Before choosing a material, the designer should be aware of the following properties. Note that these properties for different common materials are often already collected and are available in various forms from manufacturers or in various textbooks.

## Tensile Strength

The tensile strength, or tensile stress, of a material is the maximum amount of stress it can withstand before fracture. Proof stress, or yield stress, is similar, but measures that maximum amount of stress a material can withstand before deformation becomes permanent. Figure 1 below demonstrates where tensile strength (point u) and yield stress (point y) lay on the stress-strain curve for a material. There are standard tensile tests that measure tensile strength; however, strength is a common material property that is often already tabulated (Towler et al., 2013).

Figure 1: The stress strain curve for a typical ductile material (Engineering Archives)

In addition to considerations such as the pressure of the process, there are often guidelines that specify maximum allowable stress. One such set of guidelines is laid out by ASME in their Boiler and Pressure Vessel Code (Towler et al., 2013). This should be consulted while designing pressure vessels. There are also equations that can estimate these values. The maximum pressure that a cylindrical vessel can withstand is given by the following equations, where t is shell thickness, p is pressure, R is the inside vessel radius, and S is the allowable tensile stress:

$t = {p * R \over {0.9 * S - 0.6 * p}}$

$p = {0.9 * S * t \over {R + 0.6 * t}}$

There are tabulations of S for various metals found in Perry’s Handbook (Ulrich, 1984).

## Modulus of Elasticity

The modulus of elasticity of a material, sometimes called its stiffness, measures the amount a material deforms when a certain amount of stress is placed on it. This measure applies when elastic deformation occurs, that is, when all deformation is reversible and is linearly proportional to stress (Callister et al., 2011). In Figure 1, the modulus of elasticity for the material would apply between the origin and point y. This is important because it measures the resistance of a material to bending and buckling (Towler et al., 2013).

## Ductility

Ductility measures the amount a material will deform before it fractures (Towler et al., 2013). The equation for ductility is as follows:

$\%EL={{l_f - l_0} \over l_o} * 100\%$ (Callister et al., 2011).

When a material has very low ductility it is defined as brittle. For example, in Figure 1 above, point f will be much closer to point u for a brittle material than for a ductile material. Brittle materials undergo very little deformation before they fracture, which means that in processes, there can be very little warming before a rupture. Some materials have a ductile-brittle transition points at low temperature. While these materials generally exhibit ductile properties, at low enough temperatures, they will not deform and will exhibit brittle fracture (Peters et al., 2003).

## Hardness

The material’s ability to resist plastic deformation such as dents (Towler et al., 2013). There are many simple and relatively inexpensive tests, such as Rockwell Hardness Tests and Brinell Hardness Tests, which can determine the hardness of a material. It is useful to know the hardness of a material because it can be used to predict other mechanical properties such as tensile strength and can often be easier to determine (Callister et al., 2011). Figure 2 below shows an example of the correlation between Brinell hardness number and tensile strength.

Figure 2: Tensile strength versus hardness for various materials (VanAken, 2001)

## Fatigue Resistance

Fatigue is failure of a material that can occur when there is cyclic loading on equipment, for example, in pumps. It can also occur if there are cycles of temperature or pressure (Towler et al., 2013). When there is cyclic loading, failure can occur at lower stress levels than the normal tensile strength. Fatigue failure is generally very similar to brittle failure with very little plastic deformation (Callister et al., 2011).

## Other considerations

There are many other properties to consider while selecting a material. For example, creep is the amount a material deforms while it is under constant tensile stress over long periods of time and can especially be a problem for metals at high temperatures. Other considerations include the ease of fabrication, including welding ability and flexibility, the availability and cost of material, thermal conductivity (which is especially important for equipment like heat exchangers), electrical resistance, and magnetic properties for certain cases (Towler et al., 2013).

# Process Considerations

Before choosing a material for a process, basic information must be collected, including temperature, pressure, and chemicals involved. The properties could affect the choice of materials.

## Process Temperature and Pressure

In addition to knowledge of the average temperature a process with operate at, the engineer must be aware of the maximum and minimum temperature that could occur. While picking materials, the effect of temperature of material properties must be considered. Higher temperatures generally decrease the tensile strength and elastic modulus of metals (Towler et al., 2013).

Additionally, very low temperatures can cause some materials to brittle fracture. Therefore, if the minimum process temperature is below the minimum allowable temperature for a material, a different material (such as low temperature carbon steel) must be selected. Note that the expected, maximum, and minimum environmental conditions should be considered in addition to internal conditions.

Table 1: Recommended materials for strength at high and low temperatures (Biegler et al., 1997)
High temperature service Low temperature service
T_max (F) Steel T_min (F) Steel
950 Carbon steel -50 Carbon steel
1300 330 stainless steel -75 Nickel steel (A203)
1500 Stainless steels (304,321,347,316) -320 Nickel steel (A325)
2000 Cast stainless, HC -425 Stainless steels (302,304,310,347)

Similarly, the maximum and minimum pressures must be examined in relation to material properties. Different materials have different tensile stresses which affect that maximum pressure that can be used. When internal pressure is less than external pressure (that is, the process operates in a vacuum), either materials with higher allowable tensile stresses should be used or thickness should be increased.

## Corrosion

If a process included certain corrosive chemicals such as oxygen, special allocations must be made for the materials. Additionally, environmental conditions such as salt from a nearby ocean should be considered. If corrosion is expected, the engineer should consider this in the material selection. This could involve picking a material that is naturally corrosive-resistant or by coating the inside of the pipe of equipment. These coatings can be made of paint or other organic coatings, especially for resistance to atmospheric corrosion (Towler et al., 2013). For internal protection, materials can be lined with rubber, glass, stainless steel or various polymers (Ulrich, 1984; Turton et al., 2012).

## Cycling

Cycling occurs when a certain aspect of a process (temperature, pressure, or material levels) continually cycles between high and low levels. Cycling puts additional stress on the system and should be considered when selecting materials (Callister et al., 2011).

# Common Materials

## Metals

Carbon steel and stainless steels are some of the most common metals used in construction. Carbon steel is an alloy between carbon and iron. Also known as mild steel, carbon steel is one of the most commonly used engineering materials. It is favored because it is relatively cheap and widely available. It also has good tensile strength and ductility. However, carbon steel is not generally resistant to corrosion which can be an issue in many environments. When corrosion is expected, stainless steel is often favored. Stainless steel, especially with higher levels of chromium, is more resistant to corrosion (Towler et al., 2013). Stainless steel is also a better choice for low temperatures, as it has a minimum rating of -425 F, as opposed to the minimum rating of carbon steel of -50 F. Stainless steels are also a better choice than carbon steel when temperatures above 1000 F are expected (Biegler et al., 1997)

Other options include nickel and alloys, including Monel, a nickel-copper alloy (Ulrich, 1984). These are also corrosion-resistant to sulfuric and hydrocholoric acids and salt water. Nickel-chromium alloys are good to chemical resistance at high temperatures (Turton et al., 2012). Copper and alloys have the advantage of corrosion resistance and good thermal conductivity. Thus, copper is often favored for heat transfer equipment (Ulrich, 1984). Aluminum and its alloys are more moderately priced than copper metals, are lightweight, and are better for low temperatures than carbon steel, however, they have lower strength and can also be susceptible to corrosion (Ulrich, 1984). Aluminum is often appropriate for cryogenic operations (Turton et al., 2012).

Table 2: Metal properties (Towler et al., 2013)
Material Tensile strength (N/mm^2) Modulus of elasticity (kN/mm^2) Brinell Hardness Specific Gravity Max Allowable Stress (ksi) Relative Cost
Mild (carbon) steel 430 210 100-200 7.9 12.9 1
Stainless steel >540 210 160 8.0 20 2.0-3.0
Copper 200 110 30-100 8.9 6.7 22.8
Nickel 500 210 80-150 8.9 10 39.2
Monel 650 170 120-250 8.8 18.7 16.4
Titanium 500 110 150 4.5 10 6.8

## Plastics

Plastics are becoming more commonly used when corrosion is expected. Plastics are also favored because they are inexpensive. However, they have low strength compared to metals (Ulrich, 1984). Plastics can be subdivided into several categories. The first of these is thermoplastic materials, which soften with increasing temperature. PVC falls within this category, and is the most commonly used thermoplastic material in chemical plants. The second category is thermosetting materials, which have a more rigid structure due to cross-linking. Rubber is also often used in linings for tanks and pipes (Towler et al., 2013). Table 3 lists some properties of common plastics.

Table 3: Mechanical Properties and Relative Costs of Polymers (Towler et al., 2013)
Material Tensile Strength (N/mm^2) Elastic Modulus (kN/mm^2) Density (kg/m^3) Relative Cost
PVC 55 3.5 1400 1.5
Polyethylene (low density) 12 0.2 900 1.0
Polypropylene 35 1.5 900 1.5
PTFE 21 1.0 2100 30.0

## Inorganic Nonmetals

Inorganic nonmetals include glass, stoneware, brick and cements (Peters et al., 2003). Ceramics are generally stronger than other materials, especially at higher temperatures, they are much more brittle (Ulrich, 1984). Glass is good for corrosion resistance; stoneware is generally corrosive-resistant with more strength, but has poor thermal conductivity (Peters et al., 2003).

# Case Study

Chlorobenzene is produced by reacting liquid benzene with gaseous chlorine. The reaction takes place at 328K and 2.4 bar. If both the feeds are at 293K and atmospheric pressure, what are appropriate materials for the inlet piping and the reactor? (Adapted from Chemical Engineering Design (Towler et al., 2013)).

Both benzene and dry chlorine are not corrosive and therefore, carbon steel can be used as the inlet piping. Note that if the gaseous chlorine is actually wet chlorine, it becomes very corrosive to most metals and a plastic should likely be used. While the reactor is at higher pressure than atmospheric pressure, it is well below the maximum allowable stress for all common materials (Towler et al., 2013). However, a side product of the reactor is HCl which is corrosive. Likely, the HCl concentration will not be high enough to corrode the material but this should be investigated further. If concentration is >50% either in the reactor or later in the process, another material such as a plastic should be

# References

Biegler LT, Grossmann IE, Westerberg AW. Systematic Methods of Chemical Process Design. Upper Saddle River: Prentice Hall; 1997.

Callister W, Rethwisch D. Materials Science and Engineering. Wiley: New York, 2011.

Engineering Archives Website. Stress Strain Diagram. http://www.engineeringarchives.com/les_mom_stressstraindiagram.html.

Peters MS, Timmerhaus KD. Plant Design and Economics for Chemical Engineers. 5th ed. New York: McGraw Hill; 2003.

Towler G, Sinnott R. Chemical Engineering Design: Principles, Practice and Economics of Plant and Process Design. 2nd ed. Boston: Elsevier; 2013.

Turton R, Bailie RC, Whiting WB, Shaewitz JA, Bhattacharyya D. Analysis, Synthesis, and Design of Chemical Processes. 4th ed. Upper Saddle River: Prentice-Hall; 2012.

Ulrich, GD. A Guide to Chemical Engineering Process Design and Economics. Wiley: New York, 1984.

VanAken D. Industrial Heating Website [Internet]. Relationship between hardness and strength [updated 2001 Mar 7; cited 2015 Mar 1]. Available from: http://www.industrialheating.com/articles/84495-engineering-concepts-relationship-between-hardness-and-strength?v=preview.